- can
propagate through the
alkene of a
vinylogous carboxylate. Likewise, 3-dimethylaminoacrolein is the
vinylogous-amide
analog of dimethylformamide. Due...
- of the bond
gives rise to
characteristic reactivity,
which is
termed vinylogous: In
allyl compounds,
where the next
carbon is
saturated but substituted...
-
followed by tautomerization, to form the
phenolic benzannulated product. The
vinylogous Wolff rearrangement consists of a β,γ-unsaturated
diazo ketone undergoing...
- "In-Depth
Mechanistic Study on the
Formation of
Acrylamide and
Other Vinylogous Compounds by the
Maillard Reaction".
Journal of
Agricultural and Food...
-
Humulone (α-lupulic acid), a
vinylogous type of
organic acid, is a bitter-tasting
chemical compound found in the
resin of
mature hops (Humulus lupulus)...
-
acids are the
direct union of a
carbonyl group and a
hydroxyl group. In
vinylogous carboxylic acids, a carbon-carbon
double bond
separates the
carbonyl and...
- by
nucleophiles at the β-carbon. This
pattern of
reactivity is
called vinylogous.
Examples of
unsaturated carbonyls are
acrolein (propenal),
mesityl oxide...
- Bibcode:1994AdM.....6..405M. doi:10.1002/adma.19940060515. ISSN 0935-9648. The
Vinylogous Aldol Reaction: A Valuable, Yet
Understated Carbon-Carbon Bond-Forming...
- in polar, hydrogen-bonding solvents, such as water. The enol form is a
vinylogous analogue of a
carboxylic acid.
Acetylacetone is a weak acid. It forms...
-
vinylogous 2β
analogues Data-set
congruent to, and
aggregate with,
preceding table IC50 nM
values Structure S. Singh's
alphanumeric ****ignation R [3H]Mazindol...