- In
organosulfur chemistry, a
thioketal is the
sulfur analogue of a
ketal (R2C(OR)2), with one of the
oxygen replaced by
sulfur (as
implied by the thio-...
- The
Mozingo reduction, also
known as
Mozingo reaction or
thioketal reduction, is a
chemical reaction capable of
fully reducing a
ketone or
aldehyde to...
- beverages. Aminal, a.k.a.
aminoacetal Hemiaminal Orthoformate Thioacetal Thioketal IUPAC,
Compendium of
Chemical Terminology, 2nd ed. (the "Gold Book") (1997)...
- 15227/orgsyn.021.0036. S. R. Wilson, G. M.
Georgiadis (1990). "Mecaptans from
Thioketals:
Cyclododecyl Mercaptan".
Organic Syntheses;
Collected Volumes, vol. 7...
- reaction,
gives the
synthetic equivalent of an acyl anion.
Mozingo reduction Thioketal IUPAC,
Compendium of
Chemical Terminology, 2nd ed. (the "Gold Book") (1997)...
-
involves a 1,2
nucleophilic addition. This reaction, the
formation of a
thioketal,
transforms the
enzyme from its
inactive to
active state.
Inhibition of...
-
intermediate shown at
lower left in the figure,
which has the form of a hemi
thioketal. In the next step, as TPP
departs as a
leaving group,
taking electrons...
-
involves the
cleavage of
benzyl ethers: R−OCH2C6H5 + H2 → R−OH + CH3C6H5
Thioketals undergo hydrogenolysis using Raney nickel in the
Mozingo reduction. Laboratory...
-
influenced the
organosulfur chemistry by the
synthesis of
thioacetals and
thioketals.
These substances were
subsequently used by
other scientists, for example...
-
reduction can be emplo**** when
formation of the
hydrazone fail,
including thioketal reduction with
Raney nickel or
reaction with
sodium triethylborohydride...
