-
triacetoxyborohydride (STAB, NaBH(OAc)3) is a
common reducing agent for
reductive aminations. STAB
selectively reduces the
imine intermediate formed through dehydration...
-
Amination is the
process by
which an
amine group is
introduced into an
organic molecule. This type of
reaction is
important because organonitrogen compounds...
- 1021/ja00092a058 Guram, A.S.; Buchwald, S.L. (1994), "Palladium-Catalyzed
Aromatic Aminations with in situ
Generated Aminostannanes", J. Am. Chem. Soc., 116 (17): 7901–7902...
-
Other electron-deficient, sp3
amination reagents react by
similar mechanisms to give
substitution products. In
aminations involving oxaziridines, nucleophilic...
-
selective iridium catalysts with (R,R,R)-phosphoramidite L The
allylic aminations of a wide
variety of
achiral allylic esters proceeded with
total conversion...
-
Transamination is a
chemical reaction that
transfers an
amino group to a
ketoacid to form new
amino acids.This
pathway is
responsible for the deamination...
- 1-N-iminipyridinium
ylides leads in high
yields to 1H-1,2-diazepines N-
amination of 1H-benzotriazole with hydroxylamine-O-sulfonic acid
yields a mixture...
-
hydrogens (hydrogenolysis).
Ammonium formate can be used for
reductive amination of
aldehydes and
ketones (Leuckart reaction), by the
following reaction:...
-
catalyst can
effect both
branched and
linear regioselective allylic C-H
aminations. In
order to
promote nucleophilic attack at the
internal terminus of the...
-
Deamination is the
removal of an
amino group from a molecule.
Enzymes that
catalyse this
reaction are
called deaminases. In the
human body, deamination...
