-
called the
allylic position or
allylic site. A
group attached at this site is
sometimes described as
allylic. Thus, CH2=CHCH2OH "has an
allylic hydroxyl...
- An
allylic rearrangement or
allylic shift is an
organic chemical reaction in
which reaction at a
center vicinal to a
double bond
causes the
double bond...
-
Allylic strain (also
known as A1,3 strain, 1,3-
allylic strain, or A-strain) in
organic chemistry is a type of
strain energy resulting from the interaction...
- The Tsuji–Trost
reaction (also
called the
Trost allylic alkylation or
allylic alkylation) is a palladium-catalysed
substitution reaction involving a substrate...
- of
olefins at the
allylic position. Today, selenium-dioxide-mediated
oxidation of
methylene groups to
alpha ketones and at the
allylic position of olefins...
-
chemical reaction to
prepare 2,3-epoxyalcohols from
primary and
secondary allylic alcohols. The
oxidizing agent is tert-butyl hydroperoxide. The
method relies...
- that
involves the
reduction of α,β-epoxy
ketones using hydrazine to give
allylic alcohols. This reaction,
introduced in 1961 by P. S. Wharton, is an extension...
- the
University of Illinois. The
catalyst has been used in a
variety of
allylic C-H
functionalization reactions of α-olefins. In addition, it has been...
- and plasticizers.
Allyl alcohol is the
smallest representative of the
allylic alcohols.
Allyl alcohol is
produced commercially by the Olin and S****...
- The
epoxidation of
allylic alcohols is a
class of
epoxidation reactions in
organic chemistry. One
implementation of this
reaction is the
Sharpless epoxidation...