- In chemistry,
ambident is a
molecule or
group that has two
alternative and
interacting reaction sites, to
either of
which a bond may be made
during a reaction...
- Kornblum's rule (after
Nathan Kornblum)
which states that in
reactions with
ambident nucleophiles (nucleophiles that can
attack from two or more places), the...
- as
compared to that of the
original electrophile.[citation needed] An
ambident nucleophile is one that can
attack from two or more places,
resulting in...
- Lurie,
Arnold P. (1959). "Heterogeneity as a
Factor in the
Alkylation of
Ambident Anions:
Phenoxide Ions1,2".
Journal of the
American Chemical Society. 81...
- Martin; Hampel, Nathalie; Ofial,
Armin R.; Mayr,
Herbert (2019-06-26). "
Ambident Reactivity of
Phenolate Anions Revisited: A
Quantitative Approach to Phenolate...
- With two
often nearly equivalent sites of attack,
epoxides are
examples "
ambident substrates." The
regioselectivity of ring-opening in
asymmetric epoxides...
- Lurie,
Arnold P. (1959). "Heterogeneity as a
Factor in the
Alkylation of
Ambident Anions:
Phenoxide Ions1,2".
Journal of the
American Chemical Society. 81...
-
reaction is the
formation of an
isonitrile because the
cyanide ion is an
ambident nucleophile and
according to Kornblum's rule is
capable of
reacting with...
- can also
compete with
alkylation on the ring
since the
aryloxide is an
ambident nucleophile.
Ullmann condensation for the
formation of bis-aryl ethers...
- bronze, br****, and pewter.
amalgam Any
alloy of
mercury with
another metal.
ambident A
molecule or
functional group that has two
alternative and interacting...
