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Silylation is the
introduction of one or more (usually)
substituted silyl groups (R3Si) to a molecule.
Silylations are core
methods for
production of organosilicon...
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laboratory gl****ware,
making the
surfaces more lipophilic. By the
process of
silylation,
polar functional groups such as
alcohols and
amines readily undergo reaction...
- Volumes, vol. 8, p. 616. Kuwajima, I.; Nakamura, E.; Hashimoto, K. (1990). "
Silylation of
Ketones with
Ethyl Trimethylsilacetate: (Z)-3-Trimethylsiloxy-2-Pentene"...
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organosilicon compounds is
found to be very
efficient and
replaced TMSCl reagent.
Silylation of
glutamic acid with
excess hexamethyldisilazane and
catalytic TMSCl...
- rn01923. ISBN 9780470842898.
Stalling DL,
Gehrke CW,
Zumwalt RW. A new
silylation reagent for
amino acids bis(trimethylsilyl)trifluoroacetamide (BSTFA)...
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trifluoromethanesulfonic acid. It is
commonly used as a
Lewis acid catalyst, e.g. in
silylations. A
white powder, zinc
triflate is
commercially available,
though some...
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which all have an
abundance of
hydroxyl groups.
Silanization differs from
silylation,
which usually refers to
attachment of
organosilicon groups to molecular...
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deprotection methods are too
harsh for the substrate. The
mechanism involves silylation of the
carbonyl oxygen and
elimination of tert-butyl
iodide (1), methanolysis...
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Kerry N. Betz,
Alexey Fedorov,
Brian Stoltz,
Robert H.
Grubbs (2015). "
Silylation of C–H
bonds in
aromatic heterocycles by an Earth-abundant
metal catalyst"...
- chloride.
Related to its
tendency to hydrolyze,
TMSOTf is
effective for
silylation of alcohols: (CH3)3SiO3SCF3 + ROH + Et3N → ROSi(CH3)3Si + [Et3NH]O3SCF3...
