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Organocadmium chemistry describes the
physical properties, synthesis, reactions, and use of
organocadmium compounds,
which are
organometallic compounds...
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Dimethylcadmium is the
organocadmium compound with the
formula Cd(CH3)2. It is a colorless,
highly toxic liquid that
fumes in air. It is a
linear molecule...
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significant rate only at
elevated temperatures,
whereas the
corresponding organocadmium and
organozinc compounds (and most
metal alkyls in general) hydrolyze...
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defluorination to
generate F− and
difluorocarbene (CF2). Some
organocopper and
organocadmium compounds have been
developed as
trifluoromethylation reagents. Fluoroform...
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yield the
tertiary alcohol. The
reaction of acyl
halides with
certain organocadmium reagents stops at the
ketone stage. The
reaction with
Gilman reagents...
- written.[7][8] The
mechanism is
sampled from the
proposed mechanism for
organocadmium compounds,
given that the
mechanisms are
identical to one
another the...
- and an
organozinc compound. By the
reaction of an acid
chloride with
organocadmium compounds or
organocopper compounds. The Dakin–West
reaction provides...
-
always divalent and
usually two-coordinate and
linear geometry.
Unlike organocadmium and
organozinc compounds,
organomercury compounds do not
react with...
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organorhodium chemistry,
organopalladium chemistry,
organosilver chemistry,
organocadmium chemistry,
organoindium chemistry,
organotin chemistry, organoantimony...
- more
closely resembles organopalladium chemistry and
contrasts with
organocadmium compounds. Electron-rich arenes, such as phenol,
undergo mercuration...
