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Organozinc chemistry is the
study of the
physical properties, synthesis, and
reactions of
organozinc compounds,
which are
organometallic compounds that...
- cross-coupling reaction. The
reaction couples organic halides or
triflates with
organozinc compounds,
forming carbon-carbon
bonds (C-C) in the process. A palladium...
- Simmons–Smith
reaction is an
organic cheletropic reaction involving an
organozinc carbenoid that
reacts with an
alkene (or alkyne) to form a cyclopropane...
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Diethylzinc (C2H5)2Zn, or DEZ, is a
highly pyrophoric and
reactive organozinc compound consisting of a zinc
center bound to two
ethyl groups. This colourless...
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organozinc reagents, such as
those used in the
palladium catalyzed Negishi coupling with aryl
halides or
vinyl halides. In such
cases the
organozinc compound...
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usually two-coordinate and
linear geometry.
Unlike organocadmium and
organozinc compounds,
organomercury compounds do not
react with water. They usually...
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Organozincs have
similar reactivity to
Grignard reagents but are much less nucleophilic, and they are
expensive and
difficult to handle.
Organozincs typically...
- Dimethylzinc, also
known as zinc methyl, DMZ, or DMZn, is an
organozinc compound with the
chemical formula Zn(CH3)2. It
belongs to the
large series of...
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coupling is a
coupling reaction taking place between a
thioester and an
organozinc halide in the
presence of a
palladium catalyst. The
reaction product is...
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application as an
activated source of zinc
required for
formation of an
organozinc reagent in the Simmons–Smith
cyclopropanation of alkenes. The
couple has...
