- nasturtiums, and capers. The S-oxides of
thiocarbonyl compounds are
known as
thiocarbonyl S-oxides: (R2C=S=O, and
thiocarbonyl S,S-dioxides or sulfenes, R2C=SO2)...
- (from
Ancient Gr**** θεῖον (theion) 'sulfur'; also
known as
thiones or
thiocarbonyls) are
organosulfur compounds related to
conventional ketones in which...
-
thionoester fission, as in a
total synthesis of azadirachtin:
Other thiocarbonyl reagents can
replace the
thioacyl chloride. In one
variation the reagent...
- (Z)-propanethial S-oxide), a
member of a
class of
organosulfur compounds known as
thiocarbonyl S-oxides (formerly "sulfines"), is a
volatile liquid that acts as a lachrymatory...
- An
ylide (/ˈɪlaɪd/) or ylid (/ˈɪlɪd/) is a
neutral dipolar molecule containing a
formally negatively charged atom (usually a carbanion)
directly attached...
- XY=SO.
IUPAC considers the term 'sulfine' obsolete,
preferring instead thiocarbonyl S-oxide;
despite this, the use of the term
sulfine still predominates...
-
source material,
carbon monosulfide, is unstable. Thus, the
synthesis of
thiocarbonyl complexes requires indirect routes, such as the
reaction of disodium...
- of the
molecule is
almost planar as are the
three H
atoms nearest the
thiocarbonyl group. This can be
explained by
models of
electron delocalisation. Thiosemicarbazides...
- the
faster the
carbonyl group will be
converted into the
corresponding thiocarbonyl by Lawesson's reagent. The
chemistry of Lawesson's
reagent and related...
- (R2NCSS)2, are
disulfides but they
behave distinctly because of the
thiocarbonyl group.
Disulfide bonds are strong, with a
typical bond
dissociation energy...
