- A
silylium ion is a
reactive silyl-containing
cation with the
formula SiR+ 3. With
three rather than the
usual four
bonds to Si,
silylium ions are the...
-
highly reactive cations such as t-butyl
cation and controversially,
silylium ions.
Silylium ion
chemistry has led to
transformative developments in cationic...
-
displacement mechanism. A
silylium ion is a
silicon cation with only
three bonds and a
positive charge. The
abstraction of the
silylium ion is seen from the...
-
earth metal complexes, p-block main
group compounds (e.g. AlCl3, AN 87;
silylium cations; [E(bipy)2]3+ (E = P, As, Sb, Bi) cations;
cationic 4 coordinate...
- C6H+7 (protonated benzene) tropylium, C7H+7 (protonated tropylidene)
silylium cations, R3Si+ (protonated silylenes)
nitrenium cations, R2N+ (protonated...
- Lin, L.; Lambert, J. B. (2002). "Crystallographic
Evidence for a Free
Silylium Ion". Science. 297 (5582): 825–827. Bibcode:2002Sci...297..825K. doi:10...
-
diffusion control.
Carbene analogs N-heterocyclic
silylene Silenes, R2Si=SiR2
Silylium ions,
protonated silylenes IUPAC Chemical Nomenclature and
Structure Representation...
-
Heterolytic cleavage of the Si-H bond from PhMe2SiH by the FLP
catalyst forms a
silylium and
hydridoborate ionic complex.
Metal free
hydrogenation of unactivated...
-
hydride ∞ 1[(SiH)−] can be formed.
General organic compounds are
termed silylium ions. Klinkhammer, Karl W. (September 1997). "Tris(trimethylsilyl)silanides...
-
surprising system Ga+/HSiR3/olefin,
proof of
oxidation with
subvalent Ga+ and
silylium catalysis with
perfluoroalkoxyaluminate anions".
Chemical Science. 13 (2):...
