- (NR2) or alkyl/aryl groups.
Silylenes have been
proposed as
reactive intermediates. They are
carbene analogs.
Silylenes are
generally synthesized by...
- carbenes, N-heterocyclic
silylenes are
known to act as
ligands in a
range of
metal complexes.
Unlike most non-NHSi
silylenes which are
Lewis acidic, stable...
-
organogermanium compounds,
organotin compounds,
organolead compounds Silylenes, the
carbene counterparts Silylenoids, the
carbenoid counterparts Decamethylsilicocene...
- emplo**** in the trapping:
Another classic but
elusive family of
targets are
silylenes,
analogues of carbenes. It was
proposed that
dechlorination of dimethyldichlorosilane...
-
formation of
radical intermediates,
polysilanes decompose by
eliminating silylenes :SiH 2 or :SiHR, as the
activation energy of this
process (~210 kJ/mol)...
- 48
hours and with heat
induces cage
opening in the same
manner as the
silylene reaction to
generate H2C=P(tBuC)3.
Reaction of this
product with tBu3C3P...
- tropylium, C7H+7 (protonated tropylidene)
silylium cations, R3Si+ (protonated
silylenes)
nitrenium cations, R2N+ (protonated nitrenes)
phosphinidenium cations...
- ω-(trimethylsilyloxy)poly[oxy(dimethyl)
silylene]- co-[oxy(methyl)(2-{4-[2,2-bis(ethoxycarbonyl)vinyl]phenoxy}- 1-methyleneethyl)
silylene]- co-[oxy(methyl)(2-(4-[2...
- 2-dihalodisilane, by retro-Diels–Alder fragmentation, by
dimerization of
silylenes, by
photofragmentation of cyclopolysilanes, or by
rearrangement of silylsilylenes...
-
compounds Related compounds Methyl (CH3)
Methylidyne (CH)
Carbide (C)
Silylene (SiH2)
Except where otherwise noted, data are
given for
materials in their...
