- In chemistry,
heterolysis or
heterolytic fission (from Gr**** ἕτερος (heteros) 'different', and λύσις (lusis) 'loosening') is the
process of cleaving/breaking...
- Look up
heterolysis in Wiktionary, the free dictionary.
Heterolysis may
refer to:
Heterolysis (biology), the
apoptosis induced by
hydrolytic enzymes from...
- general,
there are two
classifications for bond cleavage:
homolytic and
heterolytic,
depending on the
nature of the process. The
triplet and
singlet excitation...
-
through the
interaction with
electromagnetic radiation.
Heterolytic bond
cleavage and
heterolytic substitution reactions can
result in the
formation of...
-
thought of and
computed stepwise as the sum of the free-energy
changes of
heterolytic bond
dissociation (A–B → A+ + :B−),
followed by one-electron reduction...
- each of the
fragments retains one of the originally-bonded electrons.
Heterolytic fragmentation is bond
cleavage where the
bonding electrons remain with...
- bond
between an
electronegative atom and a
hydrogen atom is
broken by
heterolytic fission,
which gives a
proton (H+) and a
negative ion.
Dissociation is...
-
preferred mode of
dissociation in the gas
phase (or low ε
inert solvent) is
heterolytic rather than homolytic. The ammonia-borane
adduct (H3N → BH3) is given...
-
equilibrium between them,
although sometimes dinitrogen tetroxide can
react by
heterolytic fission to
nitrosonium and
nitrate in a
medium with high
dielectric constant...
-
often limited to a
fragment that
departs with a pair of
electrons in
heterolytic bond cleavage. In this usage, a
leaving group is a less
formal but more...
