- In
organometallic chemistry,
organolithium reagents are
chemical compounds that
contain carbon–lithium (C–Li) bonds.
These reagents are
important in organic...
-
Murahashi Coupling is a
cross coupling reaction. The
coupling partners are
organolithiums and
organic halides.
Transition metal catalysts are required. The reaction...
-
August 2014). "Preparation, Properties, and Safe
Handling of
Commercial Organolithiums: Alkyllithiums,
Lithium sec-Organoamides, and
Lithium Alkoxides". Organic...
-
Warren and Wothers. He also
wrote Organolithiums:
Selectivity for Synthesis,
which concerns the use of
organolithium compounds in
organic synthetic reactions...
-
reactions that
involve very
strong bases, such as the
preparation of
organolithiums. For example,
butyllithiums are
typically supplied as a
hexane solution...
-
reactive intermediates in
organic chemistry. In
organic synthesis,
organolithium reagents and
Grignard reagents are
commonly treated and
referred to...
-
acidic proton can also form carbenes. A
geminal dihalide exposed to
organolithiums with
undergo metal-halogen
exchange and then
eliminate a
lithium salt...
- with acid- or base-catalysis.
Carbonation of a
Grignard reagent and
organolithium reagents: RLi + CO2 → RCO−2Li+ RCO−2Li+ + HCl → RCO2H + LiCl Halogenation...
-
treating copper(I)
compounds with
Grignard reagents,
terminal alkynes or
organolithium reagents; in particular, the last
reaction described produces a Gilman...
- nucleophiles, like the
carbanions provided by
Grignard reagents and
organolithium compounds react with CO2 to give carboxylates: MR + CO2 → RCO2M where...
