-
Metallate or
metalate is the name
given to any
complex anion containing a
metal ligated to
several atoms or
small groups. Look up
metallate in Wiktionary...
-
necessary for the
synthesis of many
organic molecules. In synthesis,
metallated reagents are
typically involved in
nucleophilic substitution, single-electron-transfer...
- Many
metallated paramagnetic texaphyrin species exhibit triplet-state
lifetimes in the
nanosecond range.
These results are
mirrored by
metallated PCs....
- on the
scope and
stereochemistry of the
Julia olefination with alpha-
metallated sulphone reagents emphasised the
value of this
method in
organic chemistry...
- that n-butyllithium
normally adopts. BuLi/TMEDA is able to
metallate or even
doubly metallate many
substrates including benzene, furan, thiophene, N-alkylpyrroles...
- in the molecule. Aza
enolates (also
known as
imine anions, enamides,
metallated Schiff bases, and metalloenamines) are
nitrogen analogous to enolates...
- reactivity.
Benzene can be
metallated by
alkylsodium compounds resulting in phenylsodium. The
phenylsodium is then able to
metallate other aromatic compounds...
- palladium(II), iridium(III) and ruthenium(II) from chloro-bridged ortho-
metallated metal compounds and [(OC)3Ru(Cl)(μ-Cl)]2".
Journal of
Organometallic Chemistry...
- Volumes, vol. 3, p. 185. Jarowicki, K.; Kocienski, P. J.; Qun, L. "1,2-
Metallate Rearrangement: (Z)-4-(2-Propenyl)-3-Octen-1-ol".
Organic Syntheses. 79:...
-
benzothiazole sulfone (1) with
lithium diisopropylamide (LDA)
gives a
metallated benzothiazolyl sulfone,
which reacts quickly with
aldehydes (or ketones)...
