- non-coordinating
anion derived from a carborane. I.
Krossing & I.
Raabe (2004). "
Noncoordinating Anions - Fact or Fiction? A
Survey of
Likely Candidates". Angewandte...
- [Li(12-crown-4)2]+. Many
cationic organometallic complexes are
isolated with inert,
noncoordinating counterions.
Ferrocenium tetrafluoroborate is one such example. In...
-
Euclidean geometry is a
mathematical system attributed to
ancient Gr****
mathematician Euclid,
which he
described in his
textbook on geometry, Elements...
-
tribromide (Al2Br6)
predominates in the
solid state, in
solutions in
noncoordinating solvents (e.g. CS2), in the melt, and in the gas phase. Only at high...
-
nucleophilic (explaining the high
acidity of HClO4).
Other acids of
noncoordinating anions, such as
fluoroboric acid and
hexafluorophosphoric acid are...
- is
probably the salt SCl3+Cl−,
since related salts are
known with
noncoordinating anions. In
contrast to this tetrachloride, SF4 is a
neutral molecule...
-
terminal ligands as well as
ligand exchange between dimers. Even in
noncoordinating solvents, Al-Me
exchange is fast, as
confirmed by
proton NMR spectroscopy...
-
trisolvated monomer that is
stabilized by
intermolecular hydrogen bonds. In
noncoordinating solvents, such as
aromatics or pentane, the
complex oligomers predominate...
-
Lewis acid SbCl5 (antimony pentachloride), in
dilute solution in the
noncoordinating solvent 1,2-dichloroethane with a zero DN. The
units are kilocalories...
- Brønsted
acidity of the
water adduct. In one
application (C6F5)3B
forms noncoordinating anions by
removing anionic ligands from
metal centers. Illustrative...
