-
expansion provides the
thermodynamic driving force in this case. (6)
Steroidal ketols have been
subjected to
rearrangement conditions to give
steroids of different...
- In
organic chemistry, a
hydroxy ketone (often
referred to
simply as a
ketol) is a
functional group consisting of a
ketone (>C=O)
flanked by a hydroxyl...
-
which case it
referred to as a '
ketol'. An
aldol may also use the term β-hydroxy
aldehyde (or β-hydroxy
ketone for a
ketol). The term "aldol" may
refer to...
- In enzymology, a
ketol-acid
reductoisomerase (EC 1.1.1.86) is an
enzyme that
catalyzes the
chemical reaction (R)-2,3-dihydroxy-3-methylbutanoate + NADP+...
- in
decalin or
another suitable high-boiling solvent, upon
which an Alpha-
ketol rearrangement occurs resulting in a ring-expansion, and the
formation of...
-
quickly oxidising Mn2+ to MnO− 4, and
cleaving glycols, α-****tones, α-
ketols, α-aminoalcohols, and α-diamines.
Orthoperiodate especially stabilises high...
- Gnoj, O. (1968). "One-step
procedure for the
preparation of
tertiary α-
ketols from the
corresponding ketones". The
Journal of
Organic Chemistry. 33 (8):...
- of the
reaction is an α-hydroxy–ester or an α-hydroxy-amide. The alpha-
ketol rearrangement is an
interconversion of a
hydroxyl alpha to a
carbonyl to...
- In enzymology, a D-lyxose
ketol-isomerase (EC 5.3.1.15) is an
enzyme that
catalyzes the
chemical reaction D-lyxose ⇌ {\displaystyle \rightleftharpoons...
- this
enzyme class is 2-amino-2-deoxy-D-glucose-6-phosphate
aminohydrolase (
ketol isomerizing).
Other names in
common use
include glucosaminephosphate isomerase...
