-
Depending on the relationship, such
groups can be heterotopic, homotopic,
enantiotopic, or diastereotopic.
Homotopic groups in a
chemical compound are equivalent...
- When the
nucleophile attacks butanone, the
faces are not
identical (
enantiotopic) and a
racemic product results. When the
nucleophile is a
chiral molecule...
-
hydrolysis involves the
selective reaction of one of a pair of
either enantiotopic (within the same
molecule and
related by a
symmetry plane of the molecule)...
-
other firsts (as
Koskinen notes,
first "example of
asymmetric catalysis,
enantiotopic selection, and organocatalysis"). This
observation is also of historical...
-
ionization via
enantioselective olefin complexation Enantiotopic ionization of
leaving groups Attack at
enantiotopic ends of the
allyl complex Enantioface exchange...
- the
project and
helped develop an
explanation based on the idea of
enantiotopicity to
explain how the
enzyme alcohol dehydrogenase removed hydrogen from...
-
desymmetrization (
enantiotopic group selection), in
which the
chiral palladium aryl
intermediate undergoes insertion predominantly with one of the
enantiotopic double...
- structures. The
substituent at the oxazoline's 4-position
blocks one
enantiotopic face of the substrate,
leading to enantioselectivity. This is demonstrated...
-
derived from the
hydroboration of alpha-pinene by 9-BBN, to
differentiate enantiotopic faces of a ketone.
Following workup with basic[clarification needed]...
-
reflective symmetry. The top side
approach results in the
formation of an
enantiotopic carbinolamine to give the (−)-(3aR,7aR)-3a,4,7,7a-tetrahydro-3a-hydroxy-7a-methyl-1...
