-
examples of
vicinal difunctionalization of
unsaturated carbonyl compounds exist in the literature. In one example, the
difunctionalization of
unsaturated lactone...
-
carbon atoms (i.e., in a 1,2-relationship). It may
arise from
vicinal difunctionalization. For example, the
molecule 2,3-dibromobutane
carries two vicinal...
- with
Raney nickel affords butane. When
coupled with the easy 2,5-
difunctionalization of thiophene,
desulfurization provides a
route to 1,4-disubstituted...
- The Liebeskind–Srogl
coupling reaction is an
organic reaction forming a new carbon–carbon bond from a
thioester and a
boronic acid
using a
metal catalyst...
- keto-enol
tautomerism to the
saturated carbonyl compound. In
vicinal difunctionalization the
proton is
replaced by
another electrophile.
Conjugated carbonyls...
-
Oxytrifluoromethylation of Alkenes:
Highly Efficient and
Regioselective Difunctionalization of C=C
Bonds Mediated by
Photoredox Catalysts".
Angewandte Chemie...
-
Richard R. (1991). "Living Ring-Opening
Metathesis Polymerization of 2,3-
Difunctionalized 7-Oxanorbornenes and 7-Oxanorbornadienes by Mo(CHCMe2R)(N-2,6-C6H3-i-Pr2)(O-t-Bu)2...
- Mu, Xin; Liu,
Guosheng (2016). "Palladium(II)-Catalyzed
Oxidative Difunctionalization of Alkenes: Bond
Forming at a High-Valent
Palladium Center". Accounts...
- Martin, R. (2021). "sp3 Bis-Organometallic
Reagents via
Catalytic 1,1-
Difunctionalization of
Unactivated Olefins".
Angewandte Chemie. 60 (21): 11740–11744...
-
Oxytrifluoromethylation of Alkenes:
Highly Efficient and
Regioselective Difunctionalization of C=C
Bonds Mediated by
Photoredox Catalysts".
Angewandte Chemie...