-
Pyridinium chlorochromate (PCC) is a yellow-orange salt with the
formula [C5H5NH]+[CrO3Cl]−. It is a
reagent in
organic synthesis used
primarily for oxidation...
- Pot****ium
chlorochromate is an
inorganic compound with the
formula KCrO3Cl. It is the pot****ium salt of
chlorochromate, [CrO3Cl]−. It is a water-soluble...
- such as
chromic and
dichromic acids and
chromium trioxide,
pyridinium chlorochromate (PCC), and chromate/dichromate
compounds such as
Sodium dichromate (Na2Cr2O7)...
-
displaced by
oxidation methods based on
chromates (e.g.
pyridinium chlorochromate) or
dimethyl sulfoxide (e.g.
Swern oxidation) or Dess–Martin oxidation...
- dehydration, substitution, esterification.
Oxidation with
pyridinium chlorochromate gives adipaldehyde.
Dehydration of 1,6-hexanediol
gives oxepane,...
- 3-methylbenzaldehyde (I). The
product (II) is then
oxidized by
pyridinium chlorochromate (PCC) on
silica gel to the
ketone (III) and
brominated with hydrobromic...
- respectively,
while rarely affecting unsaturated bonds.
Pyridinium chlorochromate is
generated from
chromium trioxide and
pyridinium chloride. This reagent...
- It has been
prepared by
oxidation of 1,6-hexanediol with
pyridinium chlorochromate. Hardy, P. M.; Nicholls, A. C.; Rydon, H. N. (1972). "The Hydration...
-
other compounds made from
hexavalent chromium oxide, such as
pyridinium chlorochromate and
Collins reagent.
Because of
their toxicity,
these reagents are rarely...
-
mechanistically related oxidations using pyridinium dichromate or
pyridinium chlorochromate.
Chromate esters of
allyl alcohols may
isomerize via
formal [3,3]-sigmatropic...
