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Trimethyl phosphite is an
organophosphorus compound with the
formula P(OCH3)3,
often abbreviated P(OMe)3. It is a
colorless liquid with a
highly pungent...
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tautomer phosphorous acid, H3PO3, with the
simplest example being trimethylphosphite, P(OCH3)3. Some
phosphites can be
considered esters of the dominant...
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nonpolar solvents and
their crystallinity. For example, the
homoleptic trimethylphosphite complexes {M[P(OCH3)3]5}2+ (Ni, Pd, and Pt) have been
prepared as...
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dimethylmethylphosphonate (see
figure above)
arises from the
rearrangement of
trimethylphosphite,
which is
catalyzed by
methyl iodide. In the Horner–Wadsworth–Emmons...
- reaction. For example,
methyl iodide catalyses the
conversion of
trimethylphosphite to the
phosphonate ester dimethyl methylphosphonate: P(OMe)3 → MePO(OMe)2...
- trispyrazolylborates. The
ligand is
derived from the
cationic complex of
trimethylphosphite {(C5H5)Co[P(OCH3)3]3}2+ via an
Arbuzov reaction.
Using other phosphites...
- but
rather involves attack of the
carbanion by a
second molecule of
trimethylphosphite with
concomitant cleavage of the sulfur-carbon bond. The phosphorus...
- [(CH3O)2OPBH3]−,
prepared by base
hydrolysis of the
adduct of
borane and
trimethylphosphite.
Boranophosphates have
gained attention as
structural surrogates of...
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interaction with the
carbonyl groups. The
arene can be
displaced by the
trimethylphosphite via a SN2 type
mechanism to give the fac-tricarbonyltris(trimethyl...
-
trimethylolpropane with
phosphorus trichloride or by
transesterification with
trimethylphosphite: P(OMe)3 + EtC(CH2OH)3 → 3 MeOH + EtC(CH2O)3P The
first member of...
