-
Trimethyl phosphite is an
organophosphorus compound with the
formula P(OCH3)3,
often abbreviated P(OMe)3. It is a
colorless liquid with a
highly pungent...
-
tautomer phosphorous acid, H3PO3, with the
simplest example being trimethylphosphite, P(OCH3)3. Some
phosphites can be
considered esters of the dominant...
-
nonpolar solvents and
their crystallinity. For example, the
homoleptic trimethylphosphite complexes {M[P(OCH3)3]5}2+ (Ni, Pd, and Pt) have been
prepared as...
-
dimethylmethylphosphonate (see
figure above)
arises from the
rearrangement of
trimethylphosphite,
which is
catalyzed by
methyl iodide. In the Horner–Wadsworth–Emmons...
- phenylacetate). In a more
complicated example,
phenacyl bromide reacts with
trimethylphosphite and then
sodium hydride and
methanesulfonyl azide to give a diazo...
- reaction. For example,
methyl iodide catalyses the
conversion of
trimethylphosphite to the
phosphonate ester dimethyl methylphosphonate: P(OMe)3 → MePO(OMe)2...
- but
rather involves attack of the
carbanion by a
second molecule of
trimethylphosphite with
concomitant cleavage of the sulfur-carbon bond. The phosphorus...
-
interaction with the
carbonyl groups. The
arene can be
displaced by the
trimethylphosphite via a SN2 type
mechanism to give the fac-tricarbonyltris(trimethyl...
- of
dimethyl methylphosphonate,
which is
conveniently obtained from
trimethylphosphite.
Hydrolysis of
methyldichlorophosphine yields methylphosphinic acid...
-
trimethylolpropane with
phosphorus trichloride or by
transesterification with
trimethylphosphite: P(OMe)3 + EtC(CH2OH)3 → 3 MeOH + EtC(CH2O)3P The
first member of...
