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Trimethylphosphine is an
organophosphorus compound with the
formula P(CH3)3,
commonly abbreviated as PMe3. This
colorless liquid has a
strongly unpleasant...
- Pentakis(
trimethylphosphine)tungsten (W(PMe3)5, Me=CH3) and its
physically relevant "tucked-in" isomer, [(dimethylphosphino-κP)methyl-κC]hydrotetrakis...
- Hexakis(
trimethylphosphine)tungsten is a tungsten(0)
organometallic compound with the
formula W(P(CH3)3)6. It is a
yellow crystalline solid soluble in...
-
synthesis of
organic compounds containing phosphorus,
which he
named "
trimethylphosphine" and "triethylphosphine", in
analogy with "amine" (organo-nitrogen...
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tetramethylphosphonium and the
bromide anion. It is
prepared by
treating trimethylphosphine with
methyl bromide.
Deprotonation gives methylenetrimethylphosphine...
- 3 HOC6H5 → P(OC6H5)3 + 3 HCl
Triphenylphosphite is a
precursor to
trimethylphosphine, it
serves as a
source of P3+ that is less
electrophilic than phosphorus...
-
triethylphosphine gained acceptance earlier than did the
simpler trimethylphosphine, as
illustrated by the
preparation of the
hydride complex trans-PtHCl(PEt3)2...
- present. SnBr4
forms 1:1 and 1:2
complexes with ligands, e.g. with
trimethylphosphine the
following can be produced, SnBr4.P(CH3)3 and SnBr4.2P(CH3)3. Greenwood...
-
organolithium compounds: 3 RMgX + PCl3 → PR3 + 3 MgX2 In the case of
trimethylphosphine,
triphenyl phosphite is used in
place of the
highly electrophilic...
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Pyridine N 128
Acetonitrile N 60 DMA O 112 DMSO O 105 THF O 90.4 Et2O O 78.8
Acetone O 76.0
EtOAc O 75.5
Trimethylphosphine P 97.3
Tetrahydrothiophene S 51.6...
