- the base was not
fully understood. The base was
first believed to form a
trialkyl borate (R3B-OR), in the case of a
reaction of a
trialkylborane (BR3) and...
-
phosphine oxides. Qualitatively, the
rates of
oxidation are
higher for
trialkyl vs triarylphosphines.
Faster still are
oxidations using hydrogen peroxide...
- carbon; typically, they are
organic derivatives of
borane (BH3), as in the
trialkyl boranes.
Organoboranes and -borates
enable many
chemical transformations...
-
dialkyl phosphate during pregnancy appears to
increase the risk of ADHD. In
Trialkyl phosphates, all
three hydrogens in
phosphoric acid are
replaced by alkyl...
-
structure of
cyclopentadienide and thallium. In the gas and
liquid phase,
trialkyl organothallium compounds are
monomeric and planar. In the
solid phase,...
- "Structure and
chemistry of the
aldehyde ammonias. 1-Amino-1-alkanols, 2,4,6-
trialkyl-1,3,5-hexahydrotriazines, and N,N-dialkylidene-1,1-diaminoalkanes". J....
-
solvent (such as THF);
similar chemistry should be
expected for a
triaryl or
trialkyl borane. It is
possible for some
ligands such as DMSO to bind with two or...
-
compounds of
empirical formula AlR3 and AlR1.5Cl1.5 exist. The
aluminium trialkyls and
triaryls are reactive, volatile, and
colorless liquids or low-melting...
- ligands,
while the
Hartwig group has
focused on ferrocene-derived and
trialkyl phosphine ligands. The
dramatic increase in
activity seen with
these ligands...
- The
Abramov reaction is the
related conversions of
trialkyl to α-hydroxy
phosphonates by the
addition to
carbonyl compounds. In
terms of mechanism, the...
