Definition of Transmetalate. Meaning of Transmetalate. Synonyms of Transmetalate

- Transmetalation (alt. spelling: transmetallation) is a type of organometallic reaction that involves the transfer of ligands from one metal to another...
- organomagnesium compounds are believed not the active species. Instead, they transmetalate to organomanganese compounds, which then decompose to tert-butyl radicals...
- in polar solvents copper transmetalate with the organostannane. The resulting organocuprate reagent could then transmetalate with the palladium catalyst...
- with sodium acetate and hydrogen peroxide: Organoboron compounds also transmetalate easily, especially to organopalladium compounds. In the Suzuki reaction...
- or from directed ortho-metalation. Phenylsilanes and phenylstannanes transmetalate with BBr3, followed by hydrolysis form phenylboronic acid. Aryl halides...
- first mechanism. In this mechanism, the alkyl zinc species would first transmetalate with the nickel catalyst.  Then the nickel would abstract the halide...
- cycle. This is usually achieved in situ in the presence of active transmetalating agents such as organo-magnesium, -zinc, -tin, or -boron reagents. Once...
- bis(trimethylsilyl)acetylene. These zirconium metallacycles can then be transmetalated to create functionalized stannoles which Staubitz later used in Stille...
- Initiation from a metal(II) species (either Ni or Pd) involves two monomers transmetalating onto the metal center to form a complex that can undergo reductive...
- offering selective alkyl transfer in Stille Coupling reactions. These transmetalating agents are known to be air- and moisture-stable, as well as generally...