-
reaction is
important in nature. With
metal ions,
thiolates behave as
ligands to form
transition metal thiolate complexes. The term
mercaptan is
derived from...
- electron-precise
thiolate complexes tend to be
rather nucleophilic. From the
perspective of HSAB theory,
thiolates are soft. Late
metal thiolates are
water stable...
-
Thiolate-protected gold
clusters are a type of ligand-protected
metal cluster,
synthesized from gold ions and thin
layer compounds that play a special...
- The
arylation of
alkylthiolates proceeds by the
intermediacy of
cuprous thiolates. In the case of Ullmann-type
reactions (aminations, etherifications, etc...
- bond
forms between the
attacking thiolate and the
original sulfur atom.
Thiolates, not thiols,
attack disulfide bonds. Hence, thiol–disulfide
exchange is...
-
Thiolated polymers –
designated thiomers – are
functional polymers used in
biotechnology product development with the
intention to
prolong mucosal drug...
- the most
common oxidation state with soft
ligands such as thioethers,
thiolates, and organophosphines. Au(I)
compounds are
typically linear. A good example...
-
twisted together, then
stabilized and
hardened by
disulfide bridges.
Thiolated polymers (thiomers) can form
disulfide bridges with
cysteine substructures...
-
improve cell proliferation,
making it
valuable for
biomedical applications.
Thiolated chitosan is
produced by
attaching thiol groups to the
amino groups of...
- 280 nm.
Since thiols are less
nucleophilic than
their conjugate bases,
thiolates, DTT
becomes a less
potent nucleophile as the pH falls. (2S)-2-Amino-1...
