- lead, or cadmium. The
stability of
metal thiolates parallels that of the
corresponding sulfide minerals.
Thiolates react with
carbon disulfide to give thioxanthate...
- electron-precise
thiolate complexes tend to be
rather nucleophilic. From the
perspective of HSAB theory,
thiolates are soft. Late
metal thiolates are
water stable...
- the most
common oxidation state with soft
ligands such as thioethers,
thiolates, and organophosphines. Au(I)
compounds are
typically linear. A good example...
- bond
forms between the
attacking thiolate and the
original sulfur atom.
Thiolates, not thiols,
attack disulfide bonds. Hence, thiol–disulfide
exchange is...
-
Thiolate-protected gold
clusters are a type of ligand-protected
metal cluster,
synthesized from gold ions and thin
layer compounds that play a special...
-
Thiolated polymers –
designated thiomers – are
functional polymers used in
biotechnology product development with the
intention to
prolong mucosal drug...
-
Sodium hydrosulfide is the
chemical compound with the
formula NaSH. This
compound is the
product of the half-neutralization of
hydrogen sulfide (H2S) with...
-
improve cell proliferation,
making it
valuable for
biomedical applications.
Thiolated chitosan is
produced by
attaching thiol groups to the
amino groups of...
-
Synthesis of
Anhydrous Dilithium Dulfide,
Dilithium Disulfide and
Lithium Thiolates by
Lithium Triethylborohydride Reduction of
Elemental Sulfur and Disulfides"...
- 280 nm.
Since thiols are less
nucleophilic than
their conjugate bases,
thiolates, DTT
becomes a less
potent nucleophile as the pH falls. (2S)-2-Amino-1...
