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Superelectrophilic anions are a
class of
molecular ions that
exhibit highly electrophilic reaction behavior despite their overall negative charge. Thus...
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their negative electron affinity. However, the 2017
discovery of "
superelectrophilic anions", gas
phase fragmentation products of closo-dodecaborates,...
- ; Aubke,
Friedhelm (2005-05-10). "Homoleptic, σ-Bonded
Octahedral Superelectrophilic Metal Carbonyl Cations of Iron(II), Ruthenium(II), and Osmium(II)...
- "Evidence for Carbon–Carbon Meisenheimer–Wheland
Complexes between Superelectrophilic and
Supernucleophilic Carbon Reagents".
Angewandte Chemie. 117 (21):...
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place on 3 May 2022 in Berlin.
Warneke received it for his work on
superelectrophilic anions, the
further development of the "ion soft landing" method,...
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oxidised to form
mellitic acid:
Treatment of
hexamethylbenzene with a
superelectrophilic mixture of
methyl chloride and
aluminum trichloride (a
source of Meδ⊕Cl---δ⊖AlCl3)...
- the
inferred symmetric intermediate,
which is
again gitionic and
superelectrophilic.
Water adds at the
terminal position to give an
intermediate that...
