- The
Prilezhaev reaction, also
known as the
Prileschajew reaction or
Prilezhaev epoxidation, is the
chemical reaction of an
alkene with a
peroxy acid to...
-
ketones to
esters (Baeyer-Villiger oxidation),
epoxidation of
alkenes (
Prilezhaev reaction),
conversion of
silyl enol
ethers to
silyl α-hydroxy ketones...
-
Nikolai Alexandrovich Prilezhaev, Russian: Николай Александрович Прилежаев, (Born
September 15 [O.S. 27], 1887 in
Kopossevo near
Nizhny Novgorod, died...
- used as
oxygen sources. More
typically for
laboratory operations, the
Prilezhaev reaction is emplo****. This
approach involves the
oxidation of the alkene...
- acid in
various forms is used for the
epoxidation of
various alkenes (
Prilezhaev reaction).
Useful applications are for
unsaturated fats,
synthetic and...
- CF 3COOOH + CF 3COOH + CO(NH 2) 2 In the case of neosporol, a
Prilezhaev reaction with
trifluoroperacetic acid is used to
convert a
suitable allyl...
-
organic peroxy acids is for the
conversion of
alkenes to epoxides, the
Prilezhaev reaction.
Another common reaction is
conversion of
cyclic ketones to the...
-
yield of 83% (based on NMR evidence): In the
minor reaction pathway, a
Prilezhaev epoxidation results in the
formation of thiophene-2,3-epoxide that rapidly...
-
diastereoselective reduction with
diisobutylaluminum hydride, and
finally a
Prilezhaev epoxidation with
trifluoroperacetic acid
affords scopine. Aposcopolamine...
- be
prepared by
epoxidation of
styrene with
peroxybenzoic acid, in the
Prilezhaev reaction:
Styrene oxide is
slightly soluble in water. A
trace amount of...
