-
galactose to be
absorbed slightly faster than
glucose in the
human body.
Diastereoselectivity is the
preference for the
formation of one or more than one diastereomer...
- the substrate; second, the
resulting compound undergoes one or more
diastereoselective transformations; and finally, the
auxiliary is
removed under conditions...
- In 2013,
Carreira and co-workers
reported a
highly enantio- and
diastereoselective α-allylation of
branched aldehydes. They used
chiral primary amines...
-
reaction would also be
called diastereoselective. Cram's rule
predicts the
major diastereomer resulting from the
diastereoselective nucleophilic addition to...
-
produced by a
multistep route from 3-amino-1-propanol. Regio- and
diastereoselective synthesis of 2-arylazetidines
could be
performed from appropriately...
- The Saksena–Evans
reduction is a
diastereoselective reduction of β-hydroxy
ketones to the
corresponding anti-dialcohols,
employing the
reagent tetramethylammonium...
- Furthermore,
enantiomeric purity can be
achieved by
hydrogenation of the
diastereoselective product.
Apart from amino-acids, PBM
reaction can also be used to...
-
hydride source Zn(BH4)2 also
shows 1,2 selectivity, as well as
greater diastereoselectivity. It does so by
coordinating not only to the
carbonyl oxygen but also...
- Narasaka–Prasad reduction,
sometimes simply called Narasaka reduction, is a
diastereoselective reduction of β-hydroxy
ketones to the
corresponding syn-dialcohols...
-
yield cyclopropane-fused
tetrahydroquinolines in good
yields and
diastereoselectivities.
Treatment of
these compounds with TBAF
invokes a ring-expansion...
