Definition of Pinacolborane. Meaning of Pinacolborane. Synonyms of Pinacolborane

- Pinacolborane is the borane with the formula (CH3)4C2O2BH. Often pinacolborane is abbreviated HBpin. It features a boron hydride functional group incorporated...
- acidic conditions. The B-B bond length is 1.711(6) Å. Dehydrogenation of pinacolborane provides an alternative route: 2 (CH3)4C2O2BH → (CH3)4C2O2B-BO2C2(CH3)4...
- boron trichloride to produce useful synthetic intermediates such as pinacolborane, bis(pinacolato)diboron, and pinacolchloroborane. Semipinacol rearrangement...
- catalytic hydroboration, pinacolborane and catecholborane are widely used. They also exhibit higher reactivity toward alkynes. Pinacolborane is also widely used...
- of alkenes. Hydroborations have been studied with catecholborane and pinacolborane. It is also active for the hydrosilylation of alkenes. In the presence...
- stoichiometric equivalent rather than a large excess using the cheaper pinacolborane: Unlike in ordinary electrophilic aromatic substitution (EAS) where...
- compounds, especially those derived from catecholborane and the related pinacolborane, are intermediates in transition metal-catalyzed borylation reactions...
- aryloxy groups that diminish the Lewis acidity of the boron centre. Pinacolborane adopts a similar structure. Catecholborane is less reactive in hydroborations...
- Elusive Direct Electrophilic Borylation of Nitrogen Heterocycles with Pinacolborane". Journal of the American Chemical Society. 135 (30): 10978–10981. doi:10...
- 2-migratory insertion (M.I.), a transmetalation can take place with pinacolborane (HBPin) to produce the hydroborated product and regenerate ligated copper...