-
widely used in a catalyst-free
hydroborations.
Hydroboration–oxidation
reaction Carboboration Brown, H.C. (1961). "
Hydroboration-A
Powerful Synthetic Tool"...
-
Hydroboration–oxidation
reaction is a two-step
hydration reaction that
converts an
alkene into an alcohol. The
process results in the syn
addition of...
-
experimental ease of its use, BMS has
become common in
hydroboration reactions. In
hydroborations with BMS, the
dimethylsulfide dissociates in situ, liberating...
- with Wilkinson's Catalyst:Implications for
Transition Metal-Catalyzed
Hydroborations of Alkenes".
Journal of the
American Chemical Society. 114 (24): 9350–9359...
-
hydrofunctionalization reactions including hydroacylation,
hydroboration, and
hydrosilylation of alkenes.
Hydroborations have been
studied with
catecholborane and pinacolborane...
-
substitution with
acids is not possible. In this case, one has to use the
hydroboration–oxidation reaction,
wherein the
first step, the
boron atom acts as electrophile...
- many
chemical transformations in
organic chemistry — most importantly,
hydroboration and carboboration. Most
reactions transfer a
nucleophilic boron substituent...
-
ammonia borane as byproduct. The
ratio depends on the conditions. In the
hydroboration reaction,
diborane also
reacts readily with
alkenes to form trialkylboranes...
-
known and many are
useful in
organic synthesis. Many are
produced from
hydroboration,
which employs diborane, B2H6, a
simple borane chemical, or carboboration...
-
boron carbonitride ceramics from the
borazine derivative copolymer via
hydroboration".
Inorganic Chemistry. 43 (16): 4796–8. doi:10.1021/ic035254a. PMID 15285647...
