- Bis(
pinacolato)diboron is a
covalent compound containing two
boron atoms and two
pinacolato ligands. It has the
formula [(CH3)4C2O2B]2; the
pinacol groups...
- to
produce useful synthetic intermediates such as pinacolborane, bis(
pinacolato)diboron, and pinacolchloroborane.
Semipinacol rearrangement Roger Adams...
- of
boronates from
vinyl or aryl
halides with the cross-coupling of bis(
pinacolato)diboron in
basic conditions with a
catalyst such as PdCl2(dppf). The resulting...
-
reaction with
hydroxylamine at room temperature. The
diboron compound bis(
pinacolato)diboron
reacts with
aromatic heterocycles or
simple arenes to an arylboronate...
-
sigma bonds via a transition-metal catalyst. A
common reagent is bis(
pinacolato)diboron.
Carbon monoxide reacts with
alkylboranes to form an unstable...
- reactions, can be
installed by
reaction of a
diazonium salt with bis(
pinacolato)diboron in the
presence of
benzoyl peroxide (2 mol %) as an initiator:...
-
borylation reactions have the
general formula (RO)2B-B(OR)2. For example, bis(
pinacolato)diboron (B2Pin2), and bis(catecholato)diborane (B2Cat2) are
common boron...
-
Related compounds Related compounds Diborane Diboron tetrafluoride Bis(
pinacolato)diboron
Except where otherwise noted, data are
given for
materials in...
- B2H4
Molar m**** 25.65 g·mol−1
Related compounds Related compounds Bis(
pinacolato)diboron
Diboron tetrafluoride Tetrahydroxydiborane Except where otherwise...
- olefins, Suzuki-type
reaction with
boronic esters,
borylation with bis(
pinacolato)diboron,
protonation with i-PrOH,
decarboxylative alkynylation with alkynyl...
