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Decarboxylative cross coupling reactions are
chemical reactions in
which a
carboxylic acid is
reacted with an
organic halide to form a new carbon-carbon...
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carboxylates as an aryl
anion synthon; this
synthetic strategy is the
decarboxylative cross-coupling reaction. Upon
heating in cyclohexanone,
amino acids...
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difluoride (XeF2) has
mainly been used for
radical fluorination in
radical decarboxylative fluorination reactions. In this Hunsdiecker-type reaction,
xenon difluoride...
- to give an
allene in a Crabbé reaction. One
variation is
called the
decarboxylative A3 coupling. In this
reaction the
amine is
replaced by an
amino acid...
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rearrangement is an
adaptation of the
Claisen rearrangement and
effectively a
decarboxylative allylation. The
Carroll rearrangement (1940) in the
presence of base...
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formation Decarboxylative Borylation (2017)
Decarboxylative Alkenylation (2017)
Decarboxylative Alkynylation (2017) Cu-Catalyzed
Decarboxylative Borylation...
- Guojun; Levy,
Laura M. (2006). "Synthesis of
Biaryls via
Catalytic Decarboxylative Coupling". Science. 313 (5787): 662–664. Bibcode:2006Sci...313..662G...
- R'-H sp, sp2, sp3 Cu, Fe, Pd etc.
requires oxidant or
dehydrogenation Decarboxylative cross-coupling 2000s R-CO2H sp2 R'-X sp, sp2 Cu, Pd
Requires little-to-no...
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Ketonic decarboxylation (also
known as
decarboxylative ketonization) is a type of
organic reaction involving decarboxylation,
converting two equivalents...
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ketone upon
acidic workup. The
Kolbe electrolysis is an electrolytic,
decarboxylative dimerization reaction. It gets rid of the
carboxyl groups of two acid...