- In
organic chemistry,
methylenation is a
chemical reaction that
inserts a
methylene (−CH2−)
group into a
chemical compound: A − B ⟶ A − CH 2 − B {\displaystyle...
- Takai-Oshima-Lombardo
methylenation refers to
reactions involving a
combination of zinc, a dihalomethane, and
titanium tetrachloride to
perform methylenation of carbonyl...
- In
organic chemistry, the
Lombardo methylenation is a name
reaction that
allows for the
methylenation of
carbonyl compounds with the use of Lombardo's...
- doi:10.2174/1389200003339270 Bonthrone, W. & Cornforth, J. (1969). "The
methylenation of catechols".
Journal of the
Chemical Society (9): 1202–1204. doi:10...
- degree.
Working under Hitosi Nozaki,
Takai developed a
method for the
methylenation of
enolizable ketones and
aldehydes using geminal dizinc species. After...
-
reagents in
organic synthesis. Tebbe's reagent,
which is used for the
methylenation of
esters and ketones, is
prepared from TMA and
titanocene dichloride...
- (Trimethylsilyl)methyllithium is
classified both as an
organolithium compound and an
organosilicon compound. It has the
empirical formula LiCH2Si(CH3)3...
-
chemistry Homologation reaction Kauffmann olefination Titanium–zinc
methylenation Maercker, A. Org. React. 1965, 14, 270–490. W. Carruthers, Some Modern...
-
basis of the
Kulinkovich reaction: "Lombardo's reagent" is used for
methylenation. It is
functionally related to the Dibromomethane-Zinc-Titanium(IV)...
- B. D. (1987). "A cerium(III)
modification of the
Peterson reaction:
methylenation of
readily enolizable carbonyl compounds".
Journal of
Organic Chemistry...