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Metallate or
metalate is the name
given to any
complex anion containing a
metal ligated to
several atoms or
small groups. Look up
metallate in Wiktionary...
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Other supernucleophilic metal centers include low
oxidation state carbonyl metalate anions (e.g., CpFe(CO)2–). The
following table shows the nucleophilicity...
- The
higher alkali metals are
known to
metalate even some
unactivated hydrocarbons and are
known to self-
metalate: 2 NaC2H5 → C2H4Na2 + C2H6 In the ****lyn...
- t-Butyllithium and s-butyllithium are more basic. n-BuLi can
deprotonate (that is,
metalate) many
types of C−H bonds,
especially where the
conjugate base is stabilized...
- single-electron-transfer
mechanism of the type
shown below.
Magnesium similarly metalates organohalides to give
Grignard reagents. Frankland, E. (1849). "Ueber...
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metalation is an
important class of
metalation reactions.
Metalated sulfones, acyl
groups and α-
metalated amides are
important intermediates in
chemistry synthesis...
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agent with the
empirical formula C6H5Li. It is most
commonly used as a
metalating agent in
organic syntheses and a
substitute for
Grignard reagents for...
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caused an
explosion of a 2,400 U.S.
gallons (9,100 L)-reactor used to
metalate methylcyclopentadiene with
metallic sodium,
causing the loss of four lives...
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because porphyrins and
related macrocyclic ligands are
extremely slow to
metalate,
despite favorable thermodynamics.
These low
rates are
attributed to the...
- pH it
converts to
sodium decavanadate. It is also
precursor to
exotic metalates such as [γ-PV2W10O40]5-, [α-PVW11O40]4-, and [β-PV2W10O40]5-.
Sodium metavanadate...
