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Metallate or
metalate is the name
given to any
complex anion containing a
metal ligated to
several atoms or
small groups. Look up
metallate in Wiktionary...
- that n-butyllithium
normally adopts. BuLi/TMEDA is able to
metallate or even
doubly metallate many
substrates including benzene, furan, thiophene, N-alkylpyrroles...
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boronic ester to give an ate complex. The ate
complex undergoes a 1,2-
metallate rearrangement to give the
homologated product,
which is then
further oxidised...
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Tetrachloroferrate is the
polyatomic ion
having chemical formula FeCl−4. The
metallate can be
formed when
ferric chloride (FeCl3)
abstracts a
chloride ion from...
- Volumes, vol. 3, p. 185. Jarowicki, K.; Kocienski, P. J.; Qun, L. "1,2-
Metallate Rearrangement: (Z)-4-(2-Propenyl)-3-Octen-1-ol".
Organic Syntheses. 79:...
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necessary for the
synthesis of many
organic molecules. In synthesis,
metallated reagents are
typically involved in
nucleophilic substitution, single-electron-transfer...
- Lee (2018-12-01). "Molecular
conductors of BEDT-TTF with tris(oxalato)
metallate anions" (PDF).
Coordination Chemistry Reviews. 376: 277–291. doi:10.1016/j...
- (link)
Krzysztof Jarowicki,
Philip J. Kocienski, Liu Qun (2002). "1,2-
Metallate Rearrangement: (Z)-4-(2-Propenyl)-3-Octen-1-Ol".
Organic Syntheses. 79:...
- Many
metallated paramagnetic texaphyrin species exhibit triplet-state
lifetimes in the
nanosecond range.
These results are
mirrored by
metallated PCs....
- as a
building block in
bioinorganic chemistry. The
thiometallate (see
metallate)
anion has the
distinctive property of
undergoing oxidation at the sulfur...
