- be
concluded that
hyperconjugative effects delocalize charge and
stabilize the molecule. Further, it is the
vicinal hyperconjugative effects that keep...
- spiroketals, the
orientation on the
upper left
shows stabilization by the
hyperconjugative anomeric effect twice, thus
greatly stabilizing the
orientation of...
- 426-427. ISBN 9780387448978. OCLC 154040953.
Strictly speaking, the
hyperconjugative stabilization of alkyl-substituted
carbocations is a type of three-center...
-
antiperiplanar arrangement that
facilitates interaction.
Additional hyperconjugative interaction energy stabilization is
achieved through an
increase in...
-
tetrasubstituted olefins are more
stable than
trisubstituted olefins due to
hyperconjugative stabilization. The
ratio of
enolate regioisomers is
heavily influenced...
-
shown that the
staggered conformation may be more
stable due to a
hyperconjugative effect.
Rotation away from the
staggered conformation interrupts this...
- bit shorter, and it has
reduced electronic polarizability and less
hyperconjugative stabilization of
adjacent bonds,
including developing an anti-bonding...
-
other hand, the
increase in the Cb-H bond
length implies a
strong hyperconjugative effect that is
inversely related to the
thermodynamic stability of...
- have
investigated the
predominance of the steric, electrostatic, and
hyperconjugative contributions to
rotational barriers in ethane, butane, and more substituted...
- as the dirhodium(II)tetracarboxylate carbene, is
stabilized through hyperconjugative metal enolate-type interactions.
Subsequent 1,3-dipolar cycloaddition...
