-
Homoaromaticity, in
organic chemistry,
refers to a
special case of
aromaticity in
which conjugation is
interrupted by a
single sp3
hybridized carbon atom...
- boron) for "normal"
aromatic stabilization to be available; otherwise,
homoaromaticity may be possible.
Compounds with one
heteroatom include:
Those with...
-
compounds called cyclophanes. A
special case of
aromaticity is
found in
homoaromaticity where conjugation is
interrupted by a
single sp³
hybridized carbon...
-
derived from
delocalization of
positive charge (see the
article on
homoaromaticity for details.).
Neutral systems generally require constrained geometries...
-
cyclopentene rings. List of
chemical compounds with
unusual names Azulene Homoaromaticity Nickon, Alex; Silversmith,
Ernest F. (2013).
Organic Chemistry: The...
-
alphabet (α-γ) and the
substitution pattern nomenclature common for
homoaromatic systems (ortho, meta, para) are used sometimes. Here α (ortho), β (meta)...
- 1964 in the
group of R. B.
Woodward in
connection with its
suspected homoaromatic properties—though it was
found to have no such properties—and also as...
-
Tetrahedral Topology.
Experimental Realization of Three-Dimensional
Homoaromaticity in the 1,3-Dehydro-5,7-adamantanediyl Dication".
Angewandte Chemie...
-
stability due to the
phenomenon called "three-dimensional aromaticity" or
homoaromaticity. This four-center two-electron bond
involves one pair of electrons...
-
forming three fused pentagonal cycles. The
compound may
possess weak tris-
homoaromatic character.
Oxatriquinacene has
remarkable stability compared to other...
