- ring. In some
other cases however,
enediols are
stabilized by
flanking carbonyl groups.
These stabilized enediols are
called reductones. Such species...
- are
reducing sugars,
because they can
tautomerize into
aldoses via an
enediol intermediate, and the
resulting aldehyde group can be oxidised, for example...
- versa, with a
tautomeric enediol as
reaction intermediate.
Ketoses may be
transformed into 3-ketoses, etcetera. The
enediol is also an
intermediate for...
- reaction. The
product of the
first step is
enediol-enzyme
complex that can
capture CO 2 or O 2. Thus,
enediol-enzyme
complex is the real carboxylase/oxygenase...
-
organic compounds. They are
enediols with a
carbonyl group adjacent to the
enediol group, i.e. RC(OH)=C(OH)-C(O)R. The
enediol structure is
stabilized by...
- enzyme's
active site. The
mechanism involves the
intermediate formation of an
enediol. The
relative free
energy of each
ground state and
transition state has...
-
performed with a
silyl chloride reactant to trap the
product as a
disilyl enediol ether. The
reaction is
performed in
aprotic solvents with a high boiling...
- may be
catalyzed by His99 and Asp270, and
isomerization is
likely a cis-
enediol mechanism. PMI
shows a high
degree of
selectivity for the beta
anomer of...
-
During the
catalysis by RuBisCO, an 'activated'
intermediate is
formed (an
enediol intermediate) in the
RuBisCO active site. This
intermediate is able to...
- in a
dynamic process with an enol
intermediate (more specifically, an
enediol). This
process is reversible, so
aldoses and
ketoses can be
thought of...
