-
through topochemical polymerization of 1,3-
diynes. Typically, this must
occur in the
solid state,
because many
diynes undergo both 1,2 and 1,4 polymerization...
- terbinafine.
Molecules called ene-
diynes feature a ring
containing an
alkene ("ene")
between two
alkyne groups ("
diyne").
These compounds, e.g. calicheamicin...
- A
polyyne is any
organic compound with
alternating single and
triple bonds; that is, a
series of
consecutive alkynes, (−C≡C−)n with n
greater than 1. These...
- Benzocyclobutenes, Indans, and
Tetralins via Cobalt-Catalyzed
Cooligomerization of α,ω-
diynes with
Substituted Acetylenes.
Formation and
Synthetic Utility of Trimethylsilylated...
- A. Kendrick;
Andrew B.
Holmes (1987). "1,4-Bis(trimethylsilyl)buta-1,3-
diyne".
Organic Syntheses. 65: 52. doi:10.15227/orgsyn.065.0052. Maretina, Irina...
-
cytotoxic activities.
Falcarinol and
falcarindiol (cis-heptadeca-1,9-diene-4,6-
diyne-3,8-diol) are such compounds. This
latter compound shows antifungal activity...
- an aryl
halide Fritsch–Buttenberg–Wiec****
rearrangement - can also form
diynes Glaser, Carl (1870). "Untersuchungen über
einige Derivate der Zimmtsäure"...
-
incorporated into a 10-membered
hydrocarbon ring (e.g. cyclodeca-3-ene-1,5-
diyne in
scheme 2) the reaction,
taking advantage of
increased ring
strain in...
-
preparable molecule was described.
Although long-chain and more
complex 1,4-
diynes had been
synthesized successfully before,
synthesis approaches starting...
- Danheiser, R. L.;
Denmark S. E.; Liu X. (2007), "Synthesis of
Terminal 1,3-
Diynes Via
Sonogashira Coupling of
Vinylidene Chloride Followed by Elimination...
