-
Diphosphines,
sometimes called bisphosphanes, are
organophosphorus compounds most
commonly used as
bidentate phosphine ligands in
inorganic and organometallic...
-
generally to any
chelating ligand, it is
commonly applied to
describe diphosphine ligands, as they can
adopt a wide
range of bite angles.
Diamines form...
- Bis[(2-diphenylphosphino)phenyl] ether, also
known as DPEphos, is a wide bite
angle diphosphine ligand used in
inorganic and
organometallic chemistry. The name DPEphos...
- Diphosphane, or
diphosphine, is an
inorganic compound with the
chemical formula P2H4. This
colourless liquid is one of
several binary phosphorus hydrides...
- advances.
Henri Kagan developed DIOP, an
easily prepared C2-symmetric
diphosphine that gave high ee's in
certain reactions. Ryōji
Noyori introduced the...
- 2′-bis(diphenylphosphino)-1,1′-binaphthyl) is an
organophosphorus compound. This
chiral diphosphine ligand is
widely used in
asymmetric synthesis. It
consists of a pair...
-
properties of
diphosphines makes them
especially useful in
asymmetric catalysis, e.g.
Noyori asymmetric hydrogenation.
Several diphosphines have been developed...
- Alkynylpalladium(IV) and -Platinum(IV) Species,
Including Triorgano(
diphosphine)metal(IV)
Complexes and the
Structural Study of an Alkynyl(pincer)platinum(IV)...
-
compound derived from the
heterocycle xanthene. It is used as a
bidentate diphosphine ligand and is
noteworthy for
having a
particularly wide bite
angle (108°)...
-
yields chirality in the
reaction product. An
early C2-symmetric ligand,
diphosphine catalytic ligand DIPAMP, was
developed in 1968 by
William S. Knowles...
