-
rearrangement to cyclopentadienes.
Closely related is the more
reactive dibromocarbene CBr2. The
related chlorocarbene (ClHC) can be
generated from methyllithium...
- the
geometry of the
alkene is
preserved in the product. For example,
dibromocarbene and cis-2-butene
yield cis-2,3-dimethyl-1,1-dibromocyclopropane, whereas...
- 008 g·mol−1
Related compounds Other anions Methylene Dichlorocarbene Dibromocarbene Diiodocarbene Other cations Difluorosilylene Difluorogermylene Stannous...
- reaction, with the
addition taking place in a syn manner. For example,
dibromocarbene and cis-2-butene
yield cis-2,3-dimethyl-1,1-dibromocyclopropane, whereas...
- much
simplified synthesis was
published by Szeimies. It
starts with
dibromocarbene addition to the
alkene bond of 3-chloro-2-(chloromethyl)propene 6 followed...
- process, in
which first the
alkene is
reacted with
dichlorocarbene or
dibromocarbene to form a dihalocyclopropane. This
intermediate is then
reacted with...
- and phenyl(tribromomethyl)mercury are
sources dichlorocarbenes and
dibromocarbenes, respectively. The
carbonyl ylide can be
generated upon
reaction of...
