- In
organic chemistry, a
diazirine is an
organic molecule consisting of a
carbon bound to two
nitrogen atoms,
which are double-bonded to each other, forming...
- vitro. Photo-reactive
amino acid
analogs in
common use are
photoreactive diazirine analogs to
leucine and methionine, and para-benzoylphenylalanine. Upon...
- l-Leucine
amino acid. l-photo-leucine is
characterized by the
presence of a
diazirine ring
linked to the R
radical of the
original amino acid. This cyclopropene...
-
produced from an
extrusion reaction with a
large free
energy change.
Diazirines and
epoxides photolyze with a
tremendous release in ring
strain to carbenes...
-
photoreactive diazirine analogs to
leucine and methionine,
which are
incorporated into proteins. Upon
exposure to
ultraviolet light, the
diazirines are activated...
-
functional groups are
replaced with a
photoreactive group, such as an azide, a
diazirine or a benzophenone.
Photoaffinity labeling Photoaffinity labeling, Gold...
- group, such as
ketene (ethenone) (CH2=CO),
diazomethane (linear CH2=N2),
diazirine (cyclic [−CH2−N=N−]) and
diiodomethane (I−CH2−I). The
decomposition can...
-
mammalian GABAA receptors has been
identified by
photolabeling using a
diazirine derivative. Additionally, it was
shown that the
hyaluronan polymer present...
-
Graham reaction is an
oxidation reaction that
converts an
amidine into a
diazirine using a
hypohalite reagent. The
halide of the
hypohalite oxidant, or another...
-
heteroatoms Heteroatoms Saturated Unsaturated 2 ×
Nitrogen Diaziridine Diazirine Nitrogen +
Oxygen Oxaziridine Oxazirine Nitrogen +
Sulfur Thiaziridine...
