-
substituted for a
larger group,
strain is
imposed upon the
molecule due to
diaxial interactions. This is an
interaction (that is
usually repulsive) between...
- The Fürst-Plattner rule (also
known as the trans-
diaxial effect)
describes the
stereoselective addition of
nucleophiles to
cyclohexene derivatives. Cyclohexene...
- the ring. This
effect is
abolished in
polar solvents such as water. 1,3-
diaxial interactions,
which usually destabilize the
anomer that has the anomeric...
-
conformation to
avoid the
steric strain between the substituents. 1,3-
diaxial strain is
another form of
strain similar to syn-pentane. In this case,...
-
cyclohexane ring can
achieve antiperiplanarity only when they
occupy trans diaxial positions (that is, both are in
axial position, one
going up and one going...
-
Spacecraft magnetometers are
magnetometers used
aboard spacecraft and satellites,
mostly for
scientific investigations, plus
attitude sensing. Magnetometers...
- red), the
hydride encounters 1,3-
diaxial strain. In
equatorial attack (shown in blue), the
hydride avoids the 1,3-
diaxial interaction, but the substrate...
- room)
balances the
pronaos or
porch of a temple,
creating a plan with
diaxial symmetry. The
upper portion of its
outer wall
could be
decorated with a...
- of
axial hydrogen atoms on the same side of the ring (known as the 1,3-
diaxial interactions).
There are two such interactions, with each
pairwise methyl/hydrogen...
-
apparent in the
diaxial versus diequatorial heats of
formation of cis 1,3-dialkyl cyclohexanes.
Relative to the
diequatorial conformer, the
diaxial conformer...
