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- The
Favorskii rearrangement is prin****lly a
rearrangement of
cyclopropanones and α-halo
ketones that
leads to
carboxylic acid derivatives. In the case...
- "Isolation and
structure of coprine, a
novel physiologically active cyclopropanone derivative from
Coprinus atramentarius and its
synthesis via 1-aminocyclopropanol"...
-
acetaldehyde dehydrogenase. 1-aminocyclopropanol
quickly converts to
cyclopropanone hydrate,
which binds covalently to the
thiol group present in the enzyme...
-
simplest class have the
formula (CH2)nCO,
where n
varies from 2 for
cyclopropanone ((CH2)2CO) to the tens.
Larger derivatives exist.
Cyclohexanone ((CH2)5CO)...
- form a unit
connected by
opposed arrows.) (Center
column of 3rd row)
Cyclopropanone,
cyclo (-CH2-CH2-CO-), CAS
number 5009-27-8 (Right
column of 3rd row)...
- dichlorocyclopropanes.
These can be
reduced to
cyclopropanes or
hydrolysed to give
cyclopropanones by a
geminal halide hydrolysis.
Dichlorocyclopropanes may also be converted...
- (cycloalkanone). It is a
colorless volatile liquid at room temperature.
Since cyclopropanone is
highly sensitive,
cyclobutanone is the
smallest easily handled cyclic...
- This
reactive intermediate is
postulated to
occur in ring
opening of
cyclopropanones,
allene oxides and in the
Favorskii rearrangement. The intermediate...