- Štěpán; Smrčina,
Martin (2003). "Non-Symmetrically
Substituted 1,1'-
Binaphthyls in
Enantioselective Catalysis".
Chemical Reviews. 103 (8): 3213–3246...
-
chiral atropisomers, as in
various ortho-substituted biphenyls, and in
binaphthyls such as BINAP.
Axial chirality differs from
central chirality (point...
- 1,1'-
Binaphthyl is an
organic compound with the
formula (C10H7)2. It is one of the
dimers of
naphthalene (or literally:
dimers of naphthyl). A colorless...
- trans-2-(1-pheyl-1-methylethyl)cyclohexanol have been explored. 1,1’-
Binaphthyl-2,2’-diol, or BINOL, has been used as
chiral auxiliary for the asymmetric...
- Jacques, J.; Fouquey, C. (1989). "Enantiomeriic (S)-(+)- and (R)-(−)-1,1'-
Binaphthyl-2,2'-diyl
Hydrogen Phosphate". Org. Synth. 67: 1. doi:10.15227/orgsyn...
-
substoichiometric (catalytic). Many
important chiral ligands are
constructed from the
binaphthyl scaffold and
ultimately derived from
BINOL as a
starting material, BINAP...
-
binding axially.
Developed by Noyori,
BINAP (2,2'-diphenylphosphino-1,1'-
binaphthyl) is a
family of
chiral diphosphine ligands featuring two triarylphosphine...
- "Design and
Preparation of 3,3'-Disubstituted 2,2'-Bis(oxazolyl)-1,1'-
binaphthyls (boxax): New
Chiral Bis(oxazoline)
Ligands for
Catalytic Asymmetric Wacker-Type...
- be
isolated by seed-directed
crystallization of racemates. Thus, 1,1'-
Binaphthyl crystallizes from the melt as
individual enantiomers. In one application...
-
synthesizing a
variety of
enantiopure substituted binaphthyl ligands. The most
successful of
these substituted binaphthyls,
shown below, gave 92%
product enantiomeric...
