- bases:
imines derived from anilines. The term can be
synonymous with
azomethine which refers specifically to
secondary aldimines (i.e. R−CH=NR' where...
-
Azomethine ylides are nitrogen-based 1,3-dipoles,
consisting of an
iminium ion next to a carbanion. They are used in 1,3-dipolar
cycloaddition reactions...
-
dipole or a
nucleophilic dipole,
which includes azomethine ylide,
carbonyl ylide,
nitrile ylide,
azomethine imine,
carbonyl imine and diazoalkane. These...
-
electrophilic carbenes.
Certain nitrogen-based
ylides also
exist such as
azomethine ylides with the
general structure:
These compounds can be
envisioned as...
- (R2CN(R)O) Some imines:
Azomethine imine Nitrilimines (RCN−NR,
analogous to
nitrile oxide)
Carbonyl imines Some
ylides Azomethine ylide Nitrile ylide (RCNCR'2)...
-
electron transfer),
organic electronics,
switching and sensing.
Amphoterism Azomethine ylide "Zwitterion".
Chemistry LibreTexts. 2015-11-03.
Retrieved 2022-02-11...
-
imine Names Preferred IUPAC name
Methanimine Other names Formaldimine Azomethine Formaldehyde imine Identifiers CAS
Number 2053-29-4 3D
model (JSmol) Interactive...
-
possible side-reactions: the
ketone and
proline to an oxazolidinone; and two
copies of the
aldehyde and
proline decarboxylating to an
azomethine ylide....
- Pletcher,
Terry C.; Kwolek,
Stephanie L. (August 29, 1984). "Aromatic
Azomethine Polymers and Fibers".
Polymers for
Fibers and Elastomers.
American Chemical...
- aza-Michael reaction.
Another route involves [3+2]
cycloaddition of the
azomethine ylides (e.g. (CH2)2NR) to
quinone in the
presence of
suitable catalysts...
