-
organyl substituent.
Alkoxides are
strong bases[citation needed] and, when R is not bulky, good
nucleophiles and good ligands.
Alkoxides,
although generally...
-
Silicon alkoxides are a
group of
alkoxides,
chemical compounds of
silicon and an alcohol, with the
formula Si(OR)4.
Silicon alkoxides are
important precursors...
-
Metal alkoxides are used for
coatings and as catalysts. Many
alkoxides are
prepared by salt-forming
reactions from a
metal chlorides and
sodium alkoxide: MCln...
- then the two are
reacted together. The
alkoxide (or aryloxide) may be
primary and secondary.
Tertiary alkoxides tend to give
elimination reaction because...
-
structure is more
complex than
suggested by its
empirical formula. Like
other alkoxides of titanium(IV) and zirconium(IV), it
finds used in
organic synthesis...
- the
titanium alkoxides are
often complex.
Crystalline titanium methoxide is
tetrameric with the
molecular formula Ti4(OCH3)16.
Alkoxides derived from...
- an
anhydrous base to give an ester.
Catalysts are
aluminium alkoxides or
sodium alkoxides.
Benzaldehyde reacts with
sodium benzyloxide (generated from...
-
presence of an
alkoxide. The
reaction is
named after Russian organic chemist Vyacheslav Tishchenko, who
discovered that
aluminium alkoxides are effective...
- techniques),
which involves the
hydrolysis of its
volatile halides or
alkoxides: Ta2(OEt)10 + 5 H2O → Ta2O5 + 10 EtOH 2 TaCl5 + 5 H2O → Ta2O5 + 10 HCl...
-
Issues in Cross-Coupling: Solid-State
Decomposition of
Primary Sodium Alkoxides in Air,
American Chemical Society, doi:10.26434/chemrxiv.12818234.v1,...
