Definition of Acyloins. Meaning of Acyloins. Synonyms of Acyloins

- standard oxaziridine did not result in an acyloin. Reduction of acyloins give diols. Oxidation of acyloins give diones. α-hydroxy ketones give positive...
- Acyloin condensation is a reductive coupling of two carboxylic esters using impure metallic sodium to yield an α-hydroxyketone, also known as an acyloin...
- and R−C(=O)−CH2−CH(OH)−R' (beta). Alpha-hydroxy ketones are also called acyloins. They are commonly formed by condensation or reductive coupling of two...
- aromatic aldehydes or glyoxals (OCH=CHO), and results in formation of an acyloin (−C(O)CH(OH)−). In the classic example, benzaldehyde is converted to benzoin...
- the synthesis of dithiolenes entails the reaction of α-hydroxyketones, acyloins, with P4S10 followed by hydrolysis and treatment of the mixture with metal...
- A common route to imidazol-2-ones involves condensation of ureas and acyloins. Some are of interest in the pharmaceuticals. 4-Imidazolones arise from...
- hydroxyketones and alpha hydroxy imines. Reactions of type 4 are also called acyloin rearrangements. While similar to the pinacol rearrangement, the semipinacol...
- Normally such compounds are disfavored components in equilibria with acyloins. One special case is catechol, where the C=C subunit is part of an aromatic...
- reaction mainly refers to the generation of α-hydroxy carbonyl compounds (acyloins) from ketones or esters. The reaction is carried out in a basic environment...
- cheaper oxidant. Alternatively, vicinal diols or their oxidized sequelae (acyloins or α-hydroxy acids) can be oxidized with cleavage to two aldehydes or an...