- applications).
Persistent carbenes equilibrate with
their respective dimers, the
Wanzlick equilibrium. In
organometallic species,
metal complexes with the formulae...
- The
Wanzlick equilibrium is a
chemical equilibrium between a
relatively stable carbene compound and its dimer. The
equilibrium was
proposed to
apply to...
- Hans-Werner
Wanzlick (1917-1988) was a
German chemist. A
Professor of
chemistry at the
Berlin Technical University he is
notable for work on persistent...
- cir****stances. In 1970,
Wanzlick's group generated imidazol-2-ylidene
carbenes by the
deprotonation of an
imidazolium salt.
Wanzlick as well as
Roald Hoffmann...
- in
solution without needing to form
coordination compounds. Hans-Werner
Wanzlick, Guy Bertrand, and
Anthony Arduengo were
pioneers in the
development of...
- chemistry, was
awarded the 1973
Nobel Prize in Chemistry. In 1968, Hans-Werner
Wanzlick and Karl Öfele
separately reported metal-bonded N-heterocyclic carbenes...
- be
found in all of the
classes of
cyclic concerted processes. In 1960,
Wanzlick reported that
tetraaminoethylene 1
readily dissociates into diaminocarbene...
- Hans-Werner
Wanzlick,
these results were
published under the
title "1,3,4,5-Tetraphenylimidazol-2-ylidene: The
Realization of
Wanzlick's Dream." Antimony...
- Hans-Werner
Wanzlick and E.
Schikora (1960). "Ein
nucleophiles Carben".
Chemische Berichte. 94 (9): 2389–2393. doi:10.1002/cber.19610940905. H.-W.
Wanzlick (1962)...
-
intermolecular decomposition pathways. MICs do not
dimerize according to
Wanzlick equilibrium as do
normal NHCs. This
results in
relaxed steric requirements...
