-
Tropinone is an alkaloid,
famously synthesised in 1917 by
Robert Robinson as a
synthetic precursor to atropine, a
scarce commodity during World War I...
-
species all
contain two
types of the
reductase enzymes,
tropinone reductase I and
tropinone reductase II. TRI
produces tropine and TRII
produces pseudotropine...
- reaction.
Hygrine further rearranges to
tropinone. Subsequently,
tropinone reductase I (EC 1.1.1.206)
converts tropinone to
tropine which condenses with phenylalanine-derived...
- In enzymology, a
tropinone reductase II (EC 1.1.1.236) is an
enzyme that
catalyzes the
chemical reaction pseudotropine + NADP+ ⇌{\displaystyle \rightleftharpoons...
-
tropinone reductase I (EC 1.1.1.206) is an
enzyme that
catalyzes the
chemical reaction tropine + NADP+ ⇌{\displaystyle \rightleftharpoons }
tropinone...
-
methanolysis followed by
reaction with
methylamine and succinaldehyde.
Tropinone Findlay,
Stephen P. (1957). "Concerning 2-Carbomethoxytropinone*". The...
-
retention of the
thioester from the
Claisen condensation. In
formation of
tropinone from
racemic ethyl [2,3-13C2]4(Nmethyl- 2-pyrrolidinyl)-3-oxobutanoate...
-
chemical yield. An
example of a one-pot
synthesis is the
total synthesis of
tropinone or the G****man
indole synthesis.
Sequential one-pot
syntheses can be used...
- book The Art and
Science of
Chess (Batsford, 1972). His
synthesis of
tropinone (a
precursor for
atropine & benztropine) in 1917 was not only a big step...
- raw bark. It is a
homolog of
tropinone, and can be
synthesized in a
manner analogous to the
classical Robinson tropinone synthesis,
using glutaraldehyde...
