- A
tosylhydrazone in
organic chemistry is a
functional group with the
general structure RR'C=N-NH-Ts
where Ts is a
tosyl group.
Organic compounds having...
- Bamford–Stevens
reaction is a
chemical reaction whereby treatment of
tosylhydrazones with
strong base
gives alkenes. It is
named for the
British chemist...
- The
Shapiro reaction or
tosylhydrazone decomposition is an
organic reaction in
which a
ketone or
aldehyde is
converted to an
alkene through an intermediate...
-
catecholborane to
reduce α,β-unsaturated
tosylhydrazones. The
mechanism of NaBH3CN
reduction of α,β-unsaturated
tosylhydrazones has been
examined using deuterium-labeling...
-
Organic Syntheses;
Collected Volumes, vol. 8, p. 612. X.
Creary (1990). "
Tosylhydrazone Salt Pyrolyses: Phenydiazomethanes".
Organic Syntheses;
Collected Volumes...
-
single ketone can also be
converted to the
corresponding alkene via its
tosylhydrazone,
using sodium methoxide (the Bamford–Stevens reaction) or an alkyllithium...
- Wolff-Kishner reaction. The
Caglioti modification, for instance, uses
tosylhydrazone with a
hydride donor in
milder conditions with no base; the
Myers modification...
- doi:10.1351/goldbook.H02879 Shapiro,
Robert H. (1976). "Alkenes from
Tosylhydrazones". Org. React. 23 (3): 405–507. doi:10.1002/0471264180.or023.03. ISBN 0471264180...
- THC-O-acetate
Srebnik M,
Mechoulam R (1984). "Reactions of
cannabinoid tosylhydrazones:
Stereochemical aspects". Tetrahedron. 40 (19): 3839–3843. doi:10...
- reaction, two
equivalents of
strong alkyllithium base
react with p-
tosylhydrazone compounds to
produce the vinyllithium, or upon quenching, the olefin...
